Two natural dyes containing anthocyanin are extracted from sour and sweet pomegranate from Iran. Spectrophotometric evaluation of the natural dyes in solution and on a TiO2 substrate was carried out to assess changes in the status of the natural dyes. The results show that the natural dyes indicate buthochromic shift on the TiO2 substrates. Dye-sensitized solar cells (DSSCs) are fabricated to determine the photovoltaic behaviour of each dye and the mixture of extracts.