Data on surface ozone concentration compiled for a 10-year period from 1990 to 1999 for Pune and Delhi are analyzed in terms of its frequency distribution, annual trend, diurnal variation and its relation with various meteorological and chemical parameters. It is found that the surface ozone concentration range showing highest frequency of occurrence at Pune is 0–5 ppb during winter and post-monsoon seasons and 15–20 ppb and 5–10 ppb during summer and monsoon seasons, respectively. It is 0–5 ppb at Delhi during all the seasons.