In this study, size-segregated particulate matter samples were collected in Raipur, India from July 2009 to June 2010 by using eight-stage cascade impactor sampler. The annual average concentrations and associated standard deviation of PM10, PM2.5–10, PM2.5, and PM1 were 270.5 ± 105.5, 119.6 ± 44.6, 150.9 ± 78.6, and 72.5 ± 39.0 μg/m3, respectively. The PM10 and PM2.5 levels at Raipur, India were well above the annual National Ambient Air Quality Standards of India of 60 and 40 μg/m3 for PM10 and PM2.5, respectively.